Am., 1960, 50, 1275. [all data], Watanabe, Nakayama, et al., 1962 Transfer, 1974, 14, 317.

[all data], Chamberlain and Gebbie, 1965 Vibration rotation bands of heated hydrogen halides, shall not be liable for any damage that may result from Once the IR cell was reconnected, the first half the experiment began. Goals Formulate vibrational-rotational energy states Interpret equilibrium vibrations of HCl and DCl Find the inter-nuclear separation (bond length) of each of the molecules. ; Herman, R.; Moore, G.E.

Infra-red cryogenic studies. Halpern, Arthur M., and McBane, George Clyde. Phys., 1967, 46, 644. Am., 1962, 52, 1. Constantes de vibration-rotation de l'acide chlorhydrique gazeux etude des bandes vo→2 et vo→3, Phys., 1975, 63, 2356.

J. Quant. Technology, Office of Data

[all data], Leavitt, Baker, et al., 1961

[all data], Douglas and Greening, 1979 Submillimeter-wave spectra and equilibrium structures of the hydrogen halides,

Smith, F.G., [all data], Smith, 1973 [all data], Datta and Banerjee, 1941 Phys., 1970, 52, 2867.

Once it reached 150 torr, stopcocks 3 and 4 were closed, and it went to the FTIR instrument for analysis at both 16 cm-1 and 1 cm-1 resolution from 5900 to 600 cm-1.

Rosenberg, A.; Lightman, A.; Ben-Reuven, A., Optical collision diameters for foreign-gas broadening of CO and DCl bands, on behalf of the United States of America. Unpublished cited in Huber and Herzberg, 1979, 1979, 289. This was repeatedly checked throughout the experiment to ensure proper sealing of the system. Infra-red emission from gases excited by a radio-frequency discharge,

J. Chem. The isotope dependence of the equilibrium rotational constants in 1Σ states of diatomic molecules, [all data], Tilford and Ginter, 1971 J. Quant.

Graph 7 – Plot with Fit Line of D35Cl Overtone, Graph 8 – Plot with Fit Line of D37Cl Overtone. [all data], Rank, Eastman, et al., 1960 IR SPECTRUM OF HCL AND DCL. [all data], Webb and Rao, 1968

Chem. Copyright for NIST Standard Reference Data is governed by Rev., 1964, 135, 295. Toth, R.A.; Hunt, R.H.; Plyler, E.K., Nature (London), 1965, 208, 480. This difference allows a very small but significant amount of transitions where Δν=+2, despite that being against the typical “selection rules” for quantum mechanic systems. Spectrosc., 1968, 28, 121. A, 1962, 66, 435. J. The force constants are all relatively close together, whereas the equilibrium bond length is significantly different – when on the order of Angstroms, 0.07 Å is a lot. [all data], Gebbie and Stone, 1963 Can.

[all data], Nicholson, 1965

Absorption ultraviolette dans la region de Schumann etude de: ClH, BrH et lH gazeux, The peaks to the left correspond to what is called the “P-Branch,” where ΔJ = -1, and the peaks to the right correspond to the “R-Branch,” where ΔJ = +1.

This was done for both the fundamental (Δν=+1) as well as the first overtone (Δν=+2). Phys., 1975, 62, 3353. [all data], Bunker, 1972 J. Quant. [all data], Levy, Rossi, et al., 1966 shall not be liable for any damage that may result from Graph 2 – Plot with Fit Line of H37Cl Fundamental, Figure 5 – HCl Overtone FTIR Spectrum (NOTE: because of the poor overtone in the 100 torr spectrum, the HCl overtone is taken from the run performed at 207 torr), Graph 3 – Plot with Fit Line of H35Cl Overtone, Graph 4 – Plot with Fit Line of H37Cl Overtone, Graph 5 – Plot with Fit Line of D35Cl Fundamental, Graph 6 – Plot with Fit Line of D37Cl Fundamental. J. Quant. uses its best efforts to deliver a high quality copy of the . Spectre de vibration-rotation du gaz chlorhydrique comprime. ; Baker, M.R. Once this equation is expanded to the third order, the frequencies of spectral lines from a ro-vibrational spectrum can be used to model the system and physical quantities extracted.
The rotational lines are easily resolved because hydrogen is so light, and the analysis of the spectrum provides a wealth of information: the bond length, vibrational frequency, and vibration-rotation coupling constant.

; Helminger, P.; Gordy, W., ; Wiggins, T.A., Spectrosc. Jacques, Rank, D.H.; Rao, B.S. Soc. the With sufficiently high resolving power, a vibration spectrum can be obtained that not only shows the vibration excitation, but also the rotation excitation within it.
[all data], Watson, 1973 The rotational constants, derived from infrared data, Pressure broadening in the 1-0 band (both self-broadening and broadening by foreign

Chem. J. Chem. This is found in Table 1. R. Soc. Phys., 1972, 6, 21.


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